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CHEMICAL
& PHYSICAL CHARACTERISTICS
HBM
is the result of combination between the material to be treated
and a hydraulic binder, which alters and improves the strength,
erosion resistance, durability and volume stability of the
soil or aggregate (natural, recycled or artificial) being
treated.
Hydraulic
binders, constituents and basic characteristics
Cement
Cement, here used to describe Portland cements, is a hydraulic binder or stabilising
agent because, in the presence of water, the calcium silicates and aluminates
in cement form hydrated compounds that subsequently produce a strong, hard
matrix that glue the soil or aggregate particles together. The material
that has been treated becomes part of this matrix. Cement can be used to
stabilize many soils but is most frequently used to stabilise granular
or non-cohesive soils where thorough dispersion of the cement is possible
because of the non-sticky nature of the soil.
Lime
Where cohesion prevents proper mixing, such as with medium to high plasticity
clays, stabilization is better carried using quick lime [CaO] or slaked
or hydrated lime [Ca(OH)2], which initially makes the soil friable and
more sand-like before reacting with the soil. In more detail, the lime
produces a high pH environment, which dissolves the aluminates and silicates
from clay making them available for combination with the lime. The result
is calcium silicates and aluminates and thus hydrates capable of setting
and hardening as with cement. If necessary, the strength of the structure
can be enhanced by adding cement at a second mixing stage when the friability
of the soil-lime mixture enables efficient mixing and dispersion of the
cement.
Pozzolanic
Materials
Some soils contain reactive silicates and/or aluminates. These are known as
pozzolanic soils or pozzolans. Most clays are thus pozzolans. Volcanic ashes
are also pozzolans.
Fly
Ash
Fly ashes from coal-fired electricity generation plants, also known as coal
fly ash or inthe UK as pulverised fuel ash, contain reactive silicates and
aluminates. Thus they are also pozzolans. Pozzolans react chemically with lime
and potentially respond better to lime than cement. It follows also that a
lime/fly ash combination may be used as a binder and thus as an alternative
to cement for the stabilization of granular materials.
Hydraulic
Slags
The slag from iron production, known as blast furnace slag, is a versatile
construction material since it can be used as an inert aggregate or as a cementitious
material or constituent in its own right, depending on how it is conditioned
when discharged from the blast furnace. If allowed to air-cool, an almost inert
hard crystalline material is produced which can be crushed to produce aggregate.
If quenched rapidly in water on the other hand, a vitrified (glassy) product
is produced which has hydraulic potential. This latter product is known as
granulated blast-furnace slag [gbs], which is naturally but slowly cementitious.
Gbs ground to enhance its speed of reaction is known as ground granulated blast-furnace
slag or ggbs.
Like fly ash above, ggbs is a well-known constituent of concrete, frequently
used to enhance the properties of concrete as well as allowing reductions in
cement content. Also like fly ash, gbs or ggbs can be used with lime as a stabilising
combination for the treatment of granular materials.
Clays
Treated with Slag and or Fly Ash
The lime/ggbs combination is also effective with clays, capable of matching
the potential of the lime/cement combination. In this respect, ggbs is better
suited than fly ash since it is effectively cement, whose hydraulicity or cementitious
potential is enhanced by lime. Fly ash on the other hand, being a pozzolan,
can only become hydraulic or cementitious in the presence of lime or a source
of lime. Since clay is also a pozzolan, it should be apparent that the addition
of another pozzolan i.e. fly ash, to a material that is also a pozzolan, such
as clay, is unnecessary. However when the clay is of low plasticity or the
natural silicates and aluminates in the clay are relatively unreactive, the
addition of fly ash can be very beneficial.
Steel
Slag
It is possible to utilize the lime content in the slag produced from steel
production for stabilisation purposes. This slag, known as air-cooled steel
slag [ASS], is particularly suited, when combined with gbs, to the treatment
of sands or combinations of fine and coarse aggregate.
Speed
of Reaction
Although the speed of reaction is slower than with cement stabilisation, the
use of lime stabilization or lime with fly ash or gbs or ggbs stabilisation
is a perfectly viable and proven option. More importantly however, the above
discussion illustrates the wide range of possibilities with certain materials
and that stabilisation has the flexibility to treat most available soils and
materials.
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